U of M researchers have cleared a major hurdle in the drive to build solar cells with potential efficiencies up to twice as high as current levels.
University of Minnesota researchers clear major hurdle in road to high-efficiency solar cells
Contacts: Preston Smith, University News Service, smith@umn.edu, 612-625-0552
MINNEAPOLIS / ST. PAUL (06/17/2010) —A team of University of Minnesota-led researchers has cleared a major hurdle in the drive to build solar cells with potential efficiencies up to twice as high as current levels, which rarely exceed 30 percent.
By showing how energy that is now being lost from semiconductors in solar cells can be captured and transferred to electric circuits, the team has opened a new avenue for solar cell researchers seeking to build cheaper, more efficient solar energy devices. The work is published in this week's Science.
A system built on the research could also slash the cost of manufacturing solar cells by removing the need to process them at very high temperatures.
The achievement crowns six years of work begun at the university Institute of Technology (College of Science and Engineering) chemical engineering and materials science professors Eray Aydil and David Norris and chemistry professor Xiaoyang Zhu (now at the university of Texas-Austin) and spearheaded by U of M graduate student William Tisdale.
In most solar cells now in use, rays from the sun strike the uppermost layer of the cells, which is made of a crystalline semiconductor substance—usually silicon. The problem is that many electrons in the silicon absorb excess amounts of solar energy and radiate that energy away as heat before it can be harnessed.
An early step in harnessing that energy is to transfer these "hot" electrons out of the semiconductor and into a wire, or electric circuit, before they can cool off. But efforts to extract hot electrons from traditional silicon semiconductors have not succeeded.
However, when semiconductors are constructed in small pieces only a few nanometers wide -- "quantum dots" -- their properties change.
"Theory says that quantum dots should slow the loss of energy as heat," said Tisdale. "And a 2008 paper from the University of Chicago showed this to be true. The big question for us was whether we could also speed up the extraction and transfer of hot electrons enough to grab them before they cooled. "
In the current work, Tisdale and his colleagues demonstrated that quantum dots—made not of silicon but of another semiconductor called lead selenide -- could indeed be made to surrender their "hot" electrons before they cooled. The electrons were pulled away by titanium dioxide, another common inexpensive and abundant semiconductor material that behaves like a wire.
"This is a very promising result," said Tisdale. "We've shown that you can pull hot electrons out very quickly – before they lose their energy. This is exciting fundamental science."
The work shows that the potential for building solar cells with efficiencies approaching 66 percent exists, according to Aydil.
"This work is a necessary but not sufficient step for building very high-efficiency solar cells," he said. "It provides a motivation for researchers to work on quantum dots and solar cells based on quantum dots."
The next step is to construct solar cells with quantum dots and study them. But one big problem still remains: "Hot" electrons also lose their energy in titanium dioxide. New solar cell designs will be needed to eliminate this loss, the researchers said.
Still, "I'm comfortable saying that electricity from solar cells is going to be a large fraction of our energy supply in the future," Aydil noted.
The research was funded primarily by the U.S. Department of Energy and partially by the National Science Foundation. Other authors of the paper were Brooke Timp from the University of Minnesota and Kenrick Williams from UT-Austin.
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science 18 June 2010:
ReplyDeleteVol. 328. no. 5985, pp. 1543 - 1547
DOI: 10.1126/science.1185509
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Reports
Hot-Electron Transfer from Semiconductor Nanocrystals
William A. Tisdale,1 Kenrick J. Williams,2,3,* Brooke A. Timp,2 David J. Norris,1,{dagger} Eray S. Aydil,1,{dagger} X.-Y. Zhu2,3,*,{dagger}
In typical semiconductor solar cells, photons with energies above the semiconductor bandgap generate hot charge carriers that quickly cool before all of their energy can be captured, a process that limits device efficiency. Although fabricating the semiconductor in a nanocrystalline morphology can slow this cooling, the transfer of hot carriers to electron and hole acceptors has not yet been thoroughly demonstrated. We used time-resolved optical second harmonic generation to observe hot-electron transfer from colloidal lead selenide (PbSe) nanocrystals to a titanium dioxide (TiO2) electron acceptor. With appropriate chemical treatment of the nanocrystal surface, this transfer occurred much faster than expected. Moreover, the electric field resulting from sub–50-femtosecond charge separation across the PbSe-TiO2 interface excited coherent vibrations of the TiO2 surface atoms, whose motions could be followed in real time.
1 Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455, USA.
2 Department of Chemistry, University of Minnesota, Minneapolis, MN 55455, USA.
3 Department of Chemistry and Biochemistry, University of Texas, Austin, TX 78712, USA.
* Present address: Department of Chemistry and Biochemistry, University of Texas, Austin, TX 78712, USA.
{dagger} To whom correspondence should be addressed: zhu@cm.utexas.edu (X.-Y.Z.), dnorris@umn.edu (D.J.N.), aydil@umn.edu (E.S.A.)
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